Make the Oreo Crust:
- Preheat your oven to 350°F (175°C). Lightly grease a 9-inch pie pan with butter or cooking spray.
- Crush the Oreos by pulsing them in a food processor until they form fine crumbs, or place them in a sealed plastic bag and crush with a rolling pin. You should have about 2 ½ cups of crumbs.
- Combine the Oreo crumbs with 5 tablespoons of melted butter in a medium bowl, stirring until the mixture resembles wet sand and holds together when pressed.
- Press the mixture firmly into the bottom and up the sides of your prepared pie pan, creating an even layer. Use the bottom of a measuring cup to pack it down tightly.
- Bake the crust for 8 minutes, then remove and set aside to cool slightly while you prepare the brownie layer.
Prepare the Brownie Layer:
- Melt the butter and chocolate together in a medium saucepan over low heat, stirring constantly until smooth and fully combined. Remove from heat and let cool for 5 minutes.
- Whisk in both sugars until well incorporated and the mixture is glossy.
- Add the eggs one at a time, whisking well after each addition until the mixture is smooth and thick.
- Stir in the vanilla extract.
- Combine the dry ingredients in a separate bowl: flour, cocoa powder, salt, and baking powder. Whisk together to remove any lumps.
- Fold the dry ingredients into the chocolate mixture using a rubber spatula, stirring just until no flour streaks remain. Don’t overmix.
- Pour the brownie batter into the prepared Oreo crust, spreading it evenly with a spatula.
- Bake for 25-28 minutes until the top looks set but the center is still slightly soft. A toothpick inserted near the center should come out with a few moist crumbs.
Add the Marshmallow Layer:
- Remove the pie from the oven and immediately sprinkle the mini marshmallows evenly over the hot brownie layer.
- Return to the oven for 2-3 minutes, just until the marshmallows puff up and begin to soften. Don’t let them brown.
- Remove from the oven and let cool to room temperature, about 1 hour. The marshmallows will deflate slightly as they cool.
Make the Chocolate Ganache:
- Heat the heavy cream in a microwave-safe bowl for 60-90 seconds until it just begins to simmer (or heat in a small saucepan on the stovetop).
- Pour the hot cream over the chocolate chips in a heatproof bowl. Let sit undisturbed for 2 minutes to allow the chocolate to melt.
- Add the butter, vanilla, and pinch of salt, then whisk gently until the mixture is completely smooth and glossy.
- Let the ganache cool for 10-15 minutes until it thickens slightly but is still pourable.
- Pour the ganache over the marshmallow layer, starting from the center and working outward. Use an offset spatula to spread it evenly to the edges, covering all the marshmallows.
- Refrigerate the pie for at least 2-3 hours, or until the ganache is completely set and firm.
- Slice and serve chilled or at room temperature. Use a sharp knife dipped in hot water and wiped clean between cuts for the neatest slices.